This paper describes the synthesis and characterization of a series of thiophene- and N-methylpyrrole-based low band gap polymers incorporating o-quinoid acceptors such as thienopyrazine, quinoxaline, benzothiadiazole, pyrazinoquinoxaline,...
This communication by Furstner and co-worker reported a novel rearrangement of methylenecyclopropanes 3 for the construction of variously substituted cyclobutenes and derivatives.
I am particularly interested in the preparation of cyclopropylidene bearing...
Swager et al reported the synthesis and fluorescence studies of poly(p-phenyleneethynylene)s. The experimental section, they made 4 different alkoxybenzenes using p-hydroquinone. I used this paper as a reference to synthesis a series of molecules:...
In this manuscipt, a high current low voltage carbon nanotube (CN) enabled vertical organic field-effect transistor (VOFET) is reported that have the future potential to drive the pixels in active matrix organic light emitting diode (AMLED).
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N-(4-carboxyphenyl) anthranilic acid (compound 31)
A mixture of 2-chlorobenzoic acid (1 mmol), 4-aminobenzoic acid (1 mmol), K2CO3 (2 mmol), Cu powder (0.009 mmol), and Cu2O (0.009 mmol) in 0.3 mL of 2-ethoxyethanol was refluxed at 130°C under inert...
This paper was about first total synthesis of an indole alkaloid, Spirobacillene A and the key step of this approach was a Lewis acid catalyzed spirocyclization of an anisole derivative onto a tethered ynone.
I tried to replicate some of these reactions...
Ruthenium oxide is one of the most active electrocatalytic material for oxygen evolution reaction (OER) and chlorine evolution reaction (CER). The attempts of improve its performance or to decrease the cost of the industrial electrodes resulted in many...
Solid state phosphors in the form of nanosized particles attract a lot of attention. This interest is of both fundamental and practical character. Ultrafine and homogeneous fluorescence particles can be used as biological labels and in the various lightning...
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This paper reports 1-Naphthyl-2-cyanoacetamide used as a precursor for the synthesis of different novel heterocyclic moieties such as 5-Aminopyrazole, thiazolinone, pyrazolo[1,5-a]pyrimidine, 4H-pyrazolo[3,4-d]pyrimidin-4-one and pyrazolo[3,4-d...
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This research article reports a study on the thermocehemical behaviour of halogen-containing molecules in atmospheric chemical processes. The thermodynamic and thermochemical model of these components helps in understanding the interactions in...
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This paper reports the synthesis of a new class of acrylamide thioglycoside derivatives utilizing a one-pot synthesis. Further heating of the resultant glycosides with hydrazine is reported to give pyrazole derivatives. Among those synthesized,...
Yttrium oxysulfide – Y2O2S is knows an excellent host material for the Eu(III) activated red emission phosphor, which has been used for decades in the CRT displays and conventional TV due to its excellent brightness, color purity, life time and compatibility...
The preparation of tetramethylguanidium azide was successfully carried out following the literature preparation (JOC 31, 1426 (1966)). Hydrazoic acid was prepared as a Et2O solution by adding conc HCl over 30 minutes to a ice cold solution of NaN3 in...
Review :-
1) Synthesized all compounds from Table 1 (1-8) and Table 2 (1-13). I was able to achieve higher yields than the ones reported in this paper by doubling the catalyst concentration.
2) I used excess i.e 3 mol % Palladium acetate than the...
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This paper reports the reactivity of the methylene group of 1-naphthyl-2-cyanoacetamide 1 which was tested towards different reagents. These new compounds have been reported to be characterized by elemental analysis, IR, 1HNMR, 13C NMR, and mass...
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This study reports the hydrodeoxygenation (HDO) of acetic acid. The authors have chosen a packed bed microreactor for the purpose. The reason for put forward by the authors for choosing micro reactor is its efficiency in operation under reduced...
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A convenient, clean and environmentally benign method for ‘‘on water’’ synthesis of benzothiazoles/benzothiazolines has been described. Although previous methods are available in literature for synthesis of such compounds, the ease of operation,...
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This paper reports the binding effect of some novel benzimidazole derivatives with Cu2+ metal ion by solution spectral studies. Benzimidazole complexes (1 – 6) were studied for fluorescence quenching by Cu2+ in comparison to Fe3+, Mg2+, Ag+, K+...
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This paper reports the synthesis of hexamethylenebisacetamide (HMBA) without organic solvent or gas protection via amide exchange reaction of hexamethylenediamine (HDA) with CH3CN and H2O catalysed by CuO. The authors report the method to be more...
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Deoxydehydration of glycols and epoxides catalysed by oxorhenium complexes is described in this paper. Methyl trioxorhenium (MTO) was the choice as the catalyst for the reactions. The use of other catalytic conditions for such reactions are...