Papers

With Tag: Cyanoolefins

Can't find what you are looking for? Add a listing here

Sort By

(1)

Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile†

Jos Wilting, Christian Müller, Alison C. Hewat, Dianne D. Ellis, Duncan M. Tooke, Anthony L. Spek, Dieter Vogt
Organometallics | 2005 | 10.1021/om049206p

Abstract: The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C−C...

(1)

Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η3-1-Me-C3H4)(CN)(dppb)

Alexandra Chaumonnot, Franck Lamy, Sylviane Sabo-Etienne, Bruno Donnadieu, Bruno Chaudret, Jean-Claude Barthelat, Jean-Christophe Galland
Organometallics | 2004 | 10.1021/om049706i

Abstract: Isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile is catalyzed by nickel π-allyl cyanide complexes. The C−CN bond breaking is a key step in the catalytic mechanism, as evidenced by in situ NMR monitoring and DFT studies.

Can't find what you are looking for? Add a paper here

/papers?k=cyanoolefins	0.000000	0.000000
INIT	0.005601	0.005601
_initView	0.009662	0.015263
_initViewBasic	0.001115	0.016378
_initSiteModules	0.001625	0.018003
_initRouters	0.001765	0.019768
pre dispatch _	0.014475	0.034243
pre dispatch _	0.006896	0.041139
ES Listing Search START	0.017264	0.058403
ES Listing Search END	0.014965	0.073368
Done	0.012429	0.085797

Loading...

Papers

With Tag: Cyanoolefins

Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile†

Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η3-1-Me-C3H4)(CN)(dppb)

Sign In With