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High Turnover Number and Rapid, Room-Temperature Amination of Chloroarenes Using Saturated Carbene Ligands

Shaun R. Stauffer, Sunwoo Lee, James P. Stambuli, Sheila I. Hauck, John F. Hartwig
Organic Letters | 2000 | 10.1021/ol005751k

A catalytic system for the mild amination of aryl chlorides is described. This system consists of a Pd(0) precursor and a dihydroimidazoline carbene ligand, which is generated in situ from its protonated tetrafluoroborate salt (2). Using this catalyst, aryl...

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