Dieter Unseld, Vassily V. Krivykh, Katja Heinze, Ferdinand Wild, Georg Artus, Helmut Schmalle, Heinz Berke Organometallics | 1999 | 10.1021/om9810549
With manganocenes as starting materials, stable mononuclear paramagnetic alkynyl and vinylidene and binuclear bis(vinylidene) and bis(carbyne) complexes with (RC 5 H 4 )Mn(dmpe) fragments (R = H, Me; dmpe = 1,2-bis(dimethylphosphino)ethane) have been prepared...
Daniel J. Dyer, Narsimha Sattenapally, Colleen N. Scott, Matthew E. McCarroll, Quinn A. Best Journal of the American Chemical Society | 2013 | 10.1021/ja401426s
We report the synthesis and characterization of a fluorescent probe (Hypo-SiF) designed for the detection of hypochlorous acid (HOCl) using a silicon analogue of fluorescein (SiF). The probe is regulated in an “off–on” fashion by a highly selective thioether...
Hongbum Kim, Chunguang Wang, Ju Sheng Lin, Tianwei Ma, Jinfa Du, M. Gary Newton, Chung K. Chu, Yung Chi Cheng, Kirupa Shanmuganathan, Yong Lian Zhu, S. Balakrishna Pai Journal of Medicinal Chemistry | 1996 | 10.1021/jm960098l
Since 2‘-fluoro-5-methyl-β-l-arabinofuranosyluracil (l-FMAU) has been shown to be a potent anti-HBV agent in vitro, it was of interest to study the structure−activity relationships of related nucleosides. Thus, a series of...
Ranger, M.; Rondeau, R.; Leclerc, M. Macromolecules | 1997 | 10.1021/ma970920a
Well-defined poly(2,7-fluorene) derivatives have been prepared through palladium-catalyzed couplings between various 9,9-disubstituted or 9-monosubstituted 2,7-dibromofluorenes and 2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene....
Mo(CO) 3 (NC-t-Bu) 3 was found to be a suitable catalyst for the regioselective hydrostannation of several types of alkynes, giving preferentially rise to the α-stannylated products. These products are not available under radical reaction conditions or by...
Anne E. V. Gorden, Xianghong Wu Journal of Combinatorial Chemistry | 2007 | 10.1021/cc070021q
A solution-phase parallel method for the synthesis of 2-quinoxalinol salen ligands was designed and optimized. The synthesis begins with commercially available 1,5-difluoro-2, 4-dinitrobenzene (DFDNB) and employs a sequence of five straightforward and...
Alois Fürstner, Christophe Aïssa Journal of the American Chemical Society | 2006 | 10.1021/ja061392y
Alkylidenecyclopropanes readily convert into cyclobutene derivatives on treatment with catalytic amounts of PtCl 2 . The reaction is strongly accelerated when performed under an atmosphere of CO (1 atm). The resulting cyclobutenes are isolated in good to...
An environmentally benign and highly catalyst-substrate controlled synthesis of 1,2-disubstituted and 2-substituted benzimidazoles with outstanding selectivity has been developed through grinding a mixture ofo -phenylenediamines, suitable aldehydes and an...
Gallou, I.; Eriksson, M.; Zeng, X.; Senanayake, C.; Farina, V. The Journal of Organic Chemistry | 2005 | 10.1021/jo0507643
A very convenient method for the synthesis of unsymmetrical ureas is described, based on isopropenyl carbamates. The synthetic efficiency of traditional methods for urea formation, such as use of phosgene or alkyl and aryl carbamates, is limited by the...
