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(1)

DFT Studies of Dimerization Reactions of Boroles

Zheng Wang, Yu Zhou, Ka-Ho Lee, Wai Han Lam, Rian D. Dewhurst, Holger Braunschweig, Todd B. Marder, Zhenyang Lin
Chemistry - A European Journal | 2017 | 10.1002/chem.201701737

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Mechanistic Studies of Cu(II) Binding to Amyloid-β Peptides and the Fluorescence and Redox Behaviors of the Resulting Complexes

Nakul C. Maiti, Dianlu Jiang, Andrew J. Wain, Sveti Patel, Kim L. Dinh, Feimeng Zhou
The Journal of Physical Chemistry B | 2008 | 10.1021/jp802038p

Due in large part to the lack of crystal structures of the amyloid-β (Aβ) peptide and its complexes with Cu(II), Fe(II), and Zn(II), characterization of the metal−Aβ complex has been difficult. In this work, we investigated the complexation of Cu(II) by Aβ...

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Preparation of thermally stable and soluble mesitylcopper(I) and its application in organic synthesis

Tetsuo Yazawa, Takeo Saegusa, Katsuhiko Watanabe, Tomoyuki Fujii, Tetsuo Tsuda
The Journal of Organic Chemistry | 1981 | 10.1021/jo00314a048

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(1)

A commercially available fluorescence chemosensor for copper ion and its application in bioimaging

Lijun Qu, Caixia Yin, Fangjun Huo, Yongbin Zhang, Yingqi Li
Sensors and Actuators B: Chemical | 2013 | 10.1016/j.snb.2013.04.017

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Orthosilicate-Mediated Esterification of Monosubstituted Phosphinic Acids

Yves R. Dumond, Jean-Luc Montchamp, Rhonda L. Baker
Org. Lett. | 2000 | 10.1021/ol006434g

Monosubstituted phosphinic acids are esterified with orthosilicates in excellent yields. Phosphinylidene-containing acids react selectively under these conditions, while disubstituted phosphinic acids and phosphonic acids remain unchanged. One-pot procedures...

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Silacyclohexadienylanionen bis- und tris-trimethylsilyl)-silacyclohexadiene

G Märkl, H. Höllriegl, W. Schlosser
Journal of Organometallic Chemistry | 1984 | 10.1016/s0022-328x(00)98691-1

1,1-Dialkyl(1,1-diaryl)-4-R-1-silacyclohexadienyl anions ( 1 ) are available by ether cleavage of the corresponding, 1,1-dialkyl(1,1-diaryl)-4-methoxy-4-R-1-silacyclohexa-2,5-dienes ( 4 ), or by deprotonation of the...

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Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η3-1-Me-C3H4)(CN)(dppb)

Alexandra Chaumonnot, Franck Lamy, Sylviane Sabo-Etienne, Bruno Donnadieu, Bruno Chaudret, Jean-Claude Barthelat, Jean-Christophe Galland
Organometallics | 2004 | 10.1021/om049706i

Isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile is catalyzed by nickel π-allyl cyanide complexes. The C−CN bond breaking is a key step in the catalytic mechanism, as evidenced by in situ NMR monitoring and DFT studies.

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Construction of the Bicyclo[3.1.0]hexane Template of a Conformationally Locked Carbocyclic Adenosine via an Olefin Keto-Carbene Cycloaddition

Kye Jung Shin, Hyung Ryong Moon, Clifford George, Victor E. Marquez
The Journal of Organic Chemistry | 2000 | 10.1021/jo9917691

An intramolecular olefin keto-carbene cycloaddition reaction created the bicyclo[3.1.0]hexane template 10 that was necessary for the synthesis of carbocyclic amine 15. This amine is a direct precursor to a family of rigid nucleosides that are conformationally...

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Efficient, one-pot syntheses of biologically active α-linked glycolipids

Wenjun Du, Suvarn S. Kulkarni, Jacquelyn Gervay-Hague
Chem. Commun. | 2007 | 10.1039/b702551c

Per- O -silylated galactosyl iodides undergo α-glycosidation with fully functionalized glycolipids producing biologically relevant conjugates.

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Benzobisthiazole-Based Donor–Acceptor Copolymer Semiconductors for Photovoltaic Cells and Highly Stable Field-Effect Transistors

Eilaf Ahmed, Selvam Subramaniyan, Felix S. Kim, Hao Xin, Samson A. Jenekhe
Macromolecules | 2011 | 10.1021/ma201128x

Six new donor–acceptor copolymers based on benzobisthiazole and various donor moieties (dithienosilole, dithienopyrrole, cyclopentadithiophene, carbazole, benzodithiophene, and bithiophene) were synthesized, characterized, and used in field-effect transistors...

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Enzymatic Synthesis of 7-Deoxy-N-acetylneuraminic Acid and 7-O-Methyl-N-acetylneuraminic Acid

Randall L. Hakomb; Wolfgang Fitz; Chi-Huey Wang
Tetrahedron: Asymmetry | 1994

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(2)

Paractamol or Aspirin?

Jennings Gh
BMJ | 1965 | 10.1136/bmj.1.5445.1311

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3D Printed “Earable” Smart Devices for Real-Time Detection of Core Body Temperature

Hiroki Ota, Minghan Chao, Yuji Gao, Eric Wu, Li-Chia Tai, Kevin Chen, Yasutomo Matsuoka, Kosuke Iwai, Hossain M. Fahad, Wei Gao, Hnin Yin Yin Nyein, Liwei Lin, Ali Javey
ACS Sensors | 2017 | 10.1021/acssensors.7b00247

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Macrophages provide a transient muscle stem cell niche via NAMPT secretion

Dhanushika Ratnayake, Phong D. Nguyen, Fernando J. Rossello, Verena C. Wimmer, Jean L. Tan, Laura A. Galvis, Ziad Julier, Alasdair J. Wood, Thomas Boudier, Abdulsalam I. Isiaku, Silke Berger, Viola Oorschot, Carmen Sonntag, Kelly L. Rogers, Christophe Marcelle, Graham J. Lieschke, Mikaël M. Martino, Jeroen Bakkers, Peter D. Currie
Nature | 2021 | 10.1038/s41586-021-03199-7

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Synthesis, X-ray studies, spectroscopic characterization and DFT calculations of p-tolylimido rhenium(V) complexes bearing an imidazole-based ligand

B. Machura, M. Wolff, I. Gryca
Polyhedron | 2011 | 10.1016/j.poly.2010.10.002

Novelp -tolylimido rhenium(V) complexes [Re(p-NC 6 H 4 CH 3 )X 2 (hpb)(PPh 3 )] and [Re(p-NC 6 H 4 CH 3 )(hpb) 2 (PPh 3 )]X (X = Cl, Br) have been obtained in the reactions of [Re(p-NC 6 H 4 CH 3 )X 3 (PPh 3 ) 2 ] with 2-(2-hydroxyphenyl)-1H-benzimidazole...

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Bile Acid-Based 1,2,4-Trioxanes: Synthesis and Antimalarial Assessment(1)

Singh, C.; Hassam, M.; Verma, V. P.; Singh, S. A.; Naikade, N. K.; Puri, S. K.; Maulik, P. R.; Kant, R.
Journal of Medicinal Chemistry | 2012 | 10.1021/jm301323k

A new series of bile acid-based trioxanes 23a–d, 24a–d, 25a–d, 26a, 26b, and 26d have been synthesized and assessed for their antimalarial activity against multidrug-resistant Plasmodium yoelii in Swiss mice by oral route. The antimalarial activity of these...

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Toward Optimized High-Relaxivity MRI Agents:  The Effect of Ligand Basicity on the Thermodynamic Stability of Hexadentate Hydroxypyridonate/Catecholate Gadolinium(III) Complexes

Dan M. J. Doble, Marco Melchior, Brendon O'Sullivan, Carsten Siering, Jide Xu, Valérie C. Pierre, Kenneth N. Raymond
Inorganic Chemistry | 2003 | 10.1021/ic026240s

The thermodynamic stabilities of the Gd III complexes of five hexadentate ligands which incorporate catecholate and hydroxypyridonate subunits with a range of basicities have been determined. The most stable Gd III complex at a physiological pH of 7.4 was...

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Ir-Catalyzed Direct Borylation at the 4-Position of Pyrene

Zhiqiang Liu, Yuanyuan Wang, Ying Chen, Jie Liu, Qi Fang, Christian Kleeberg, Todd B. Marder
The Journal of Organic Chemistry | 2012 | 10.1021/jo301293w

The first direct borylation of a C–H bond at the 4-position of pyrene was achieved using [Ir(COD)Cl] 2 /dtbpy as the catalyst precursor and B 2 pin 2 as the boron source. The position-related photophysical properties of pyrene derivatives are reported.

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Solid‐Phase Synthesis of RNA Analogs Containing Phosphorodithioate Linkages

Xianbin Yang
Current Protocols in Nucleic Acid Chemistry | 2017 | 10.1002/cpnc.40

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