O-(diphenylphosphinyl)hydroxylamine: preparation and some characteristic chemical reactions

  • 10.1039/p19810003284
  • Journal of the Chemical Society, Perkin Transactions 1
  • p 3284-3284,
  • journal-article


Adequate Synthesis; Improved Preparation Has Been Reported

This reaction was repeated to prepare O-diphenylphosphinyl hydroxylamine as this compound was reported to be a "less explosive" electrophilic aminating agent.  Note:  a recent improved preparation has been reported.  (DSC measurements of the isolated compound showed that this...