/paper/doi/10.1021/ja0121033 | 0.000000 | 0.000000 |
INIT | 0.002385 | 0.002385 |
_initView | 0.009120 | 0.011505 |
_initViewBasic | 0.000887 | 0.012392 |
_initSiteModules | 0.001625 | 0.014017 |
_initRouters | 0.001830 | 0.015847 |
pre dispatch _ | 0.015682 | 0.031529 |
LC::doiAction START | 0.000315 | 0.031844 |
LC::doiAction END to showListing | 0.287467 | 0.319311 |
LC::showListing START | 0.000004 | 0.319315 |
LC::showListing get reviews START | 0.003480 | 0.322795 |
ES Review Search START | 0.007719 | 0.330514 |
ES Review Search END | 0.006346 | 0.336860 |
LC::showListing get reviews END | 0.002261 | 0.339121 |
Done | 0.037130 | 0.376251 |
trans-hydrosilylation internal alkynes: notes/modifications
Trost and Ball discovered the efficient Ru-catalyst for Markovnikov hydrosilylation of terminal alkynes as well as trans-hydrosilylation of internal alkynes. This reaction is the only general method for accessing geminal alkenylsilanes via hydrosilylation of terminal...