Markovnikov Alkyne Hydrosilylation Catalyzed by Ruthenium Complexes

Zachary T. Ball, Barry M. Trost

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DOI 10.1021/ja0121033

Journal Journal of the American Chemical Society
Location p 12726-12727, Volume 123, Issue 50, 2001
Publication Type journal-article

Tags organometallic, organometalloidal compounds, colloid and surface chemistry, biochemistry, chemistry(all), catalysis
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24 Dec 2016

Anonymous

(15)

trans-hydrosilylation internal alkynes: notes/modifications

Reproducibility

Clarity

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Summary:

Trost and Ball discovered the efficient Ru-catalyst for Markovnikov hydrosilylation of terminal alkynes as well as trans-hydrosilylation of internal alkynes. This reaction is the only general method for accessing geminal alkenylsilanes via hydrosilylation of terminal...

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Markovnikov Alkyne Hydrosilylation Catalyzed by Ruthenium Complexes

Zachary T. Ball, Barry M. Trost

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trans-hydrosilylation internal alkynes: notes/modifications

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