8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules

Jaromír Plešek , Bohumír Grüner , Jan Macháček , Ivana Císařová , Josef Čáslavský

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DOI 10.1016/j.jorganchem.2007.07.026

Journal Journal of Organometallic Chemistry
Location p 4801-4804, Volume 692, Issue 22, 2007
Publication Type journal-article

Tags single crystal, x ray diffraction, nmr, molecular structure, physical and theoretical chemistry, inorganic chemistry, organic chemistry, materials chemistry, biochemistry
Publisher Link Click Here

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14 Dec 2016

Anonymous

(5)

Very useful paper for niche applications using metallacarboranes

Reproducibility

Clarity

Versatility

Covalent attachment of 1,4-dioxane to beta born of ferracarborane sandwich complexes which can be easily outfitted with many organic functional groups. Procedure worked as reported, with moderate yields of 60-70%. Higher yields were achieved at smaller scales (ca. less than 1g...

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8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules

Jaromír Plešek , Bohumír Grüner , Jan Macháček , Ivana Císařová , Josef Čáslavský

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Very useful paper for niche applications using metallacarboranes

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