Preparation of meta-polyaniline and its related poly(iminoarylene)s by nickel-catalyzed polycondensation of aryl dichlorides with aryl primary diamines

  • 10.1002/1099-0518(20001201)38:23<4194::AID-POLA40>3.0.CO;2-G
  • Journal of Polymer Science Part A: Polymer Chemistry
  • p 4194-4194, Volume 38, Issue 23,
  • Rapid Communication


Synthesis of poly(m-aniline) Table 1, Run 1

Under nitrogen, 1,3-dichlorobenzene (1 mmol) and 1,3-diaminobenzene were dissolved in toluene (15 mL). Sodium-tert-butoxide (NaO-t-Bu) (3 mmol), Ni(cod)2 (0.1 mmol), and DPPF (0.3mmol) were added to the solution at room temperature. The reaction mixture was stirred at 60°C for...